Along with the change in computer technology, the application of multimedia assisted teaching to education and research plays a critical role with the popularity of computer technology and the diverse development. Multimedia assisted teaching materials could assist teachers in teaching as well as enhance students’ autonomous learning that computer multimedia teaching has become an alternative teaching tool beyond traditional learning. With quasi-experimental study, 216 students in the automobile applied technology opened by a vocational college in Shanghai, are proceeded 16-week (3 hours per week for total 48 hours) experimental teaching. The research results show positive relations between 1.virtual reality technology and learning satisfaction, 2.virtual reality technology and learning outcome, and 3.learning satisfaction and learning outcome. According to the results, suggestions are proposed, expecting to provide automobile vocational education students with the situation close to real life acquiring required skills, knowledge, or behavior through learning processes to cultivate the automobile service talents with comprehensive technology.